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报告题目 |
Organometallic Reactivity of High-Valent Group 10 Transition Metal Complexes |
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报告时间 |
2014年2月26日14:30 |
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报告地点 |
资源环境楼939会议室 |
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报告人 |
Liviu M. Mirica |
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报告摘要： High-valent Pd and Ni complexes have been proposed to play an important role in a number of C-C and C-heteroatom bond formation reactions. In this context, a series of stable mono- and dinuclear Pd(III) complexes supported by tetradentante and tridentate N-donor ligands have been synthesized and their stoichiometric and catalytic oxidative reactivity were investigated. In addition, organometallic Ni(III) complexes relevant to cross-coupling reactions have been isolated for the first time and their reactivity was investigated in detail. The relevance of these high-valent Pd and Ni species in various other organometallic reactions will also be discussed. | |
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主办单位：化学与材料科学学院化学系 | |